Synthesis and reactivity of metal-containing monomers 72. Monomeric and polymeric metal acetylenecarboxylates and their nanocomposite products: synthesis,structures, and properties |
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| Authors: | V. A. Shershnev G. I. Dzhardimalieva D. P. Kiryukhin V. A. Zhorin A. D. Pomogailo |
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| Affiliation: | 1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
2. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation
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| Abstract: | Methods for the synthesis of a number of transition metal acetylenedicarboxylates were developed. The ways and conditions for their polymerization were studied. The polymerization of metal acetylenedicarboxylates was accompanied by the formation of polyconjugated chains. Controlled thermolysis of metal acetylenedicarboxylates yielded matrix-stabilized metal nanoparticles. The microstructures and magnetic properties of the nanocomposites obtained were examined. |
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