| 甲基丙烯酸三乙基锡酯的聚合反应动力学的研究 |
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| 引用本文： | 韩哲文,余竹卿,余茂宽,陈昆松. 甲基丙烯酸三乙基锡酯的聚合反应动力学的研究[J]. 高分子学报, 1986, 0(4): 317-320 |
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| 作者姓名： | 韩哲文 余竹卿 余茂宽 陈昆松 |
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| 作者单位： | 中国科学技术大学应用化学系，安徽大学化学系，安徽大学化学系，中国科学技术大学应用化学系 合肥，合肥 |
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| 摘 要： | <正> 有机锡聚合物可以用于防污涂料,与低分子有机锡化合物相比,具有低环境污染、长效等特点。近年来,人们对有机锡单体的合成、纯化、聚合和共聚合进行了研究,但有关动力学的研究报道甚少,而甲基丙烯酸三乙基锡酯(TETM)的聚合动力学未见报道。
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| 收稿时间： | 1975-07-11 |
STUDY ON THE KINETIC OF POLYMERIZATION OF TRIETHYLTIN METHACRYLATE |
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| HAN Zhe-wen,YU Zhu-qing,YU Mao-kuan,CHEN Kun-song. STUDY ON THE KINETIC OF POLYMERIZATION OF TRIETHYLTIN METHACRYLATE[J]. Acta Polymerica Sinica, 1986, 0(4): 317-320 |
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| Authors: | HAN Zhe-wen YU Zhu-qing YU Mao-kuan CHEN Kun-song |
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| Affiliation: | Department of Applied Chemistry; University of Science and Technology of China; Hefei |
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| Abstract: | In this paper, studies on the kinetic of polymerization of triethyltin methacrylate (TETM) in benzene solution at 60-80℃ in the presence of azobisisobutyronitrile (AIBM) were reported. It was shown that the rate equation of polymerization could be expressed as follows:Bp = Kp [TBTM]1.5 [AIBN]0.5,where [AIBN] and [TBTM] were the concentrations of the initiator and the monomer, respectively. The action energy of polymerization was found to be 16.6 kcal/mol. |
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