Heat capacity and thermodynamic properties of 1-hexadecanol |
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Authors: | J. Xing Z. -C. Tan Q. Shi B. Tong S. -X. Wang Y. -S. Li |
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Affiliation: | (1) Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland |
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Abstract: | Three different nitrocellulose (NC) samples produced from linters were investigated. DSC studies on the NC+sym-diethyldiphenylurea (C1) mixtures were carried out. The influence of storage time on their pore structures was examined using thermoporometry. The results led to conclusion that large pores are multiples of small ones. The parameter n was used to characterize the number of C1 molecules equivalent to NC ring. Its value for short storage time was about 9 but for longer time reached the value of 3. The influence of thermal history on the phase transition and porosity of the different nitrocellulose samples was different. |
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Keywords: | diethyldiphenylurea DSC melting enthalpy nitrocellulose pore structure thermoporometry |
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