An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl(CO)(PPh3)3 |
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Authors: | Doi Takashi Fukuyama Takahide Minamino Satoshi Husson Guillaume Ryu Ilhyong |
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Institution: | Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan. |
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Abstract: | When primary unsaturated alcohols were treated with a catalytic amount of RuHCl(CO)(PPh3)3 in benzene under reflux, dimerization reactions took place to give alpha-hydroxymethyl ketones as major product. |
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