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An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl(CO)(PPh3)3
Authors:Doi Takashi  Fukuyama Takahide  Minamino Satoshi  Husson Guillaume  Ryu Ilhyong
Institution:Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.
Abstract:When primary unsaturated alcohols were treated with a catalytic amount of RuHCl(CO)(PPh3)3 in benzene under reflux, dimerization reactions took place to give alpha-hydroxymethyl ketones as major product.
Keywords:
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