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Effect of domain transformation on the magnetic properties of CuxNi1−xFe2O4 ferrites
Authors:Justice Msomi  Thomas Moyo
Affiliation:a Department of Physics, Qwaqwa Campus, University of the Free State, Phuthaditjhaba 9866, South Africa
b School of Physics, Westville Campus, University of KwaZulu-Natal, Durban 4000, South Africa
Abstract:We report the effect of crossover from multi- to single-domain particles on the magnetic properties of CuxNi1−xFe2O4 (x=0 and 0.5) oxides due to grain size reduction to nanometer scale. The Mössbauer spectra for milled nanosized powder show a combination of ordered and super-paramagnetic behavior. The coercive field (HC) is found to increase with reduction in grain size (G) according to the equation HC=am+bm/G for multi-domain particles. For single-domain particles HC decreases with G according to HC=asbs/G2.
Keywords:Mixed ferrites   Nanoparticles    ssbauer spectra   Magnetizations   Coercivity
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