Effect of domain transformation on the magnetic properties of CuxNi1−xFe2O4 ferrites |
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Authors: | Justice Msomi Thomas Moyo |
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Affiliation: | a Department of Physics, Qwaqwa Campus, University of the Free State, Phuthaditjhaba 9866, South Africa b School of Physics, Westville Campus, University of KwaZulu-Natal, Durban 4000, South Africa |
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Abstract: | We report the effect of crossover from multi- to single-domain particles on the magnetic properties of CuxNi1−xFe2O4 (x=0 and 0.5) oxides due to grain size reduction to nanometer scale. The Mössbauer spectra for milled nanosized powder show a combination of ordered and super-paramagnetic behavior. The coercive field (HC) is found to increase with reduction in grain size (G) according to the equation HC=am+bm/G for multi-domain particles. For single-domain particles HC decreases with G according to HC=as−bs/G2. |
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Keywords: | Mixed ferrites Nanoparticles Mö ssbauer spectra Magnetizations Coercivity |
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