Solvent Effect on the Activation Volume of the Diels-Alder Reaction Between Tetracyanoethylene and trans,trans-1,4-Diphenyl-1,3-butadiene |
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| Authors: | Kiselev V D Shikhaab M S Iskhakova G G Konovalov A I |
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| Institution: | (1) Butlerov Research Institute of Chemistry, Kazan State University, Kazan, Tatarstan, Russia |
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| Abstract: | The effect of increased hydrostatic pressure on the rate of the Diels-Alder reaction of tetracyanoethylene with trans,trans-1,4-diphenyl-1,3-butadiene at 25°C was studied to estimate the reaction volume and to show that it considerably varies with  -donor properties of the medium. |
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