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A convenient method for the synthesis of polyfluorinated β-diimines
Authors:O E Petrova  M A Kurykin  D V Gorlov
Institution:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:The higher internal perfluoroak-2-enes react with ammonium hydroxide at atmospheric pressure to give the corresponding iminoenamines, whose further transformations yield heptafluoroacetylacetone analogs. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1710–1712, September, 1999.
Keywords:internal perfluoroolefins  ammonolysis  polyfluorinated iminoenamines  polyfluorinated β  -diketones  synthesis  heptafluoroacetylacetone
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