Inhomogeneous micropore structures and adsorption properties of carbon adsorbents. 9. Microporous adsorbents with maximum development of the micropore volume |
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Authors: | M M Dubinin O Kadlets L I Kataeva B A Onusaitis |
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Institution: | 1. Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow 2. Institute of Physical Chemistry and Electrochemistry, Academy of Sciences of Czechoslovakia, Prague
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Abstract: | 1. |
The adsorption properties with respect to benzene vapors and the pore structure of carbon adsorbents with almost maximum development of the microporosity were studied.
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The position of the micropore volume distribution curves whose maxima correspond to a size (halfwidth) of 1.2–1.4 nm and micropore volumes 1.5 cm3/g is a characteristic feature of the adsorbents studied. The difference between ordinary active carbons and the active carbons investigated is only quantitative in the values of the parameters of the Dubinin-Stockley adsorption equation.
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The adsorption isotherms are described by the adsorption equation from the theory of volume filling of micropores in a wide range of equilibrium relative pressures and temperatures of 293–353 K with totally satisfactory precision.
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The question of the upper limit of the micropores of carbon adsorbents is discussed.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 977–983, May, 1988. |
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