|
|||||
|
|
| 4,4-二乙硫／苄硫基-3-烯-2-丁酮的合成及其作为无气味硫醇替代试剂的缩硫醛/酮化反应 | |
| 引用本文： | 于海丰,王艳茹,欧阳艳,王岩,刘群.4,4-二乙硫／苄硫基-3-烯-2-丁酮的合成及其作为无气味硫醇替代试剂的缩硫醛/酮化反应[J].高等学校化学学报,2006,27(12):2300-2303. |
| 作者姓名： | 于海丰 王艳茹 欧阳艳 王岩 刘群 |
| 作者单位： | 1. 东北师范大学化学学院,长春,130024;鞍山师范学院化学系,鞍山,114005 2. 北华大学公共基础部,吉林,132013 3. 东北师范大学化学学院,长春,130024 |
| 摘 要： | 经由3-(二乙硫／苄硫基)亚甲基-2,4-戊二酮(1)的酸催化脱乙酰基反应高产率地合成了4,4-二乙硫／苄硫基-3-烯-2-丁酮(2). 化合物2作为无气味的乙硫醇及苄硫醇替代试剂能与各种醛／酮在温和的反应条件下生成相应的缩硫醛／酮. |
| 关 键 词： | α-羰基二硫缩烯酮 4 4-二乙硫／苄硫基-3-烯-2-丁酮 无气味硫醇替代试剂 缩硫醛/酮化反应 |
| 文章编号： | 0251-0790（2006）12-2300-04 |
| 收稿时间： | 11 14 2005 12:00AM |
| 修稿时间： | 2005-11-14 |
Synthesis of 4,4-Diethylthio/benzylthio-but-3-en-2-one and Application as Odorless Thiol Equivalents in Thioacetalization |
|
| YU Hai-Feng,WANG Yan-Ru,OUYANG Yan,WANG Yan,LIU Qun.Synthesis of 4,4-Diethylthio/benzylthio-but-3-en-2-one and Application as Odorless Thiol Equivalents in Thioacetalization[J].Chemical Research In Chinese Universities,2006,27(12):2300-2303. | |
| Authors: | YU Hai-Feng WANG Yan-Ru OUYANG Yan WANG Yan LIU Qun |
| Institution: | 1. Faculty of Chemistry, Northeast Normal University, Changchun 130024, China; 2. Department of Chemistry, Anshan Teachers College, Anshan 114005, China; 3. Public Foundation Department of Beihua University, Jilin 132013, China |
| Abstract: | 4,4-Diethylthio/benzylthio-but-3-en-2-ones 2 were prepared in excellent yields by the acid-catalyzed deacetylation of 3-(diethylthio/benzylthio)methylene-pentane-2,4-diones(1). With ketene diethylthio/benzylthioacetals(2) as the odorless thiol equivalents, in the presence of acetyl chloride, a series of diethylthio-/dibenzylthioacetals were prepared via the reaction of compound 2 with aldehydes/ketones in methanol under mild conditions. |
| Keywords: | α-Oxo ketene-S α-Oxo ketene-S" target="_blank">S-acetals')" href="#">α-Oxo ketene-S S-acetals 4 4-Bis(ethylthio/benzylthio)but-3-en-2-ones Odorless thiol equi-valents Thioacetalization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 | |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 | |