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Triterpene Glycosides of Astragalus and Their Genins. LXX. Orbicoside, the First Lanostane Glycoside from Astragalus Plants
Authors:R. P. Mamedova  M. A. Agzamova  M. I. Isaev
Affiliation:(1) Academy of Sciences of the Republic of Uzbekistan, S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Tashkent
Abstract:Orbicoside, a new lanostane glycoside and the first from plants of the Astragalus genus, was isolated from the aerial organs of Astragalus orbiculatus Ledeb. (Leguminosae). It has the structure 23xgr,24xgr-lanost-9(11)-en- 3beta,7beta,16beta,19,23,24,25-heptaol 3-O-beta-D-xylopyranoside. The structure of orbicoside was established using PMR and 13C NMR, which were interpreted using DEPT and 2D NMR spectroscopies 1H-1H COSY, HSQC, and HMBC.
Keywords:lanostanoids  triterpenoids  orbicoside  Astragalus  Leguminosae  PMR and 13C NMR spectra  DEPT  2D NMR: 1H-1H COSY, HSQC, HMBC
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