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Synthesis of Novel High Energy Polyaniline Derivative Containing S-S Bond in Six-membered Cycle
Authors:ZHOU Lei  Deng Shi-ren  Li Zao-ying
Abstract:A novel conducting polymer as new class of high energy storage material, 1,2] which has one six-membered cycle containing S-S bond in the moiety of aniline was synthesized. The polymer had enhanced redox progress due to an intramolecular electrocatalytic effect of polyaniline on S-S bond. The polymer has some advantages because of its high theoretical specific energy and fast kinetics when used in lithium batteries. The most promised advantage of it is that the intramolecular cleavage and recombination of the S-S bond improve the cyclicability greatly.
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