Synthesis and spectral properties of merocyanine dyes based on fluorene and its derivatives |
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Authors: | I. V. Kurdyukova N. A. Derevyanko A. A. Ishchenko D. D. Mysyk |
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Affiliation: | 1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02094, Ukraine 2. Donetsk National Technical University, Donetsk, Ukraine
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Abstract: | The di-, tetra- and hexamethine merocyaninyes, the derivatives of fluorene, diphenyl 9H-fluorene-2,7-disulfonate, and bis(2,2,3,3,4,4,5,5-octafluoropentyl) 9H-fluorene-2,7-disulfonate, as well as the derivatives of the heterocycles of moderate (indolylidene and benzotiazolylidene), weak (benzo[c,d]indolylidene and 2,6-diphenylpyrane) and strong (2,6-diphenylpyridine) electron-donor properties were synthesized and their absorption spectra in solvents of different polarity were studied. The quantum-chemical analysis of electronic structure of the synthesized merocyanines was performed and the types of electronic transitions in them were found by the DFT and TDDFT methods with the B3LYP/6-31G(d,p) basis. |
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