Liquid-phase synthesis of cyclic diene diepoxides using metal halides and hydrogen peroxide |
| |
| Authors: | Kh M Alimardanov O A Sadygov N I Garibov M Ya Abdullaeva |
| |
| Institution: | 1. Mamedaliev Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, pr. Khodzhaly 30, Baku, AZ 1025, Azerbaijan
|
| |
| Abstract: | Optimal conditions were found for induced hydroxyhalogenation of cyclic dienes (tetrahydroindene, 4-vinylcyclohexene and 5-vinyl- and 5-cyclohexenylbicyclo2.2.1]hept-2-enes) in the system MHlg-HA or HHlg]-H2O2 (or NaClO). Dehydrohalogenation of the chloro- and bromohydrins thus obtained with powdered potassium carbonate gave the corresponding diepoxy derivatives, and their hydrolysis led to mixtures of stereoisomeric tetrahydric alcohols. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
