Catalytic reaction of 1-chloropropenyl butyl ethers with methyl diazoacetate |
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| Authors: | L. N. Ivanova R. M. Sultanova S. S. Zlotsky V. A. Dokichev |
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| Affiliation: | 1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Russia
2. Ufa State Petroleum Technical University, Ufa, Russia
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| Abstract: | Catalytic reaction of trans- and cis-1-chloropropenyl butyl ethers with methyl diazoacetate catalyzed by either Rh2(OAc)3, or Cu(OTf)2, or Cu(acac)2 in the presence of the imidazolium salts [bmim]+ Cl?, [bmim]+ BF 4 ? , and [bmim]+ PF 6 ? was studied. The composition and ratio of products formed was shown to depend on the reaction conditions and the nature and ratio of the components of the catalytic system. |
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