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A novel 3D supramolecular coordination polymer based on tetranuclear complex of lead(ii) with terephthalic acid and 8-hydroxyquinolin, [Pb4(8-Quin)4(Tp)2(DMF)2] n |
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| Authors: | A. Ghaemi S. Rayati B. Jahanpanah H. R. Khavasi |
| Affiliation: | 1. Department of Chemistry, Saveh Branch, Islamic Azad University, Saveh, Iran 2. Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran 3. Department of Chemistry, Shahid Beheshti University, G.C., Evin, 1983963113, Tehran, Iran |
| Abstract: | A novel two-dimensional coordination polymer, [Pb4(8-Quin)4(Tp)2(DMF)2] n (Tp = terephthalic dianion, 8-Quin = 8-Hydroxyquinolate, and DMF = N,N-dimethylformamide) has been synthesized and characterized by elemental analysis, FT-IR, and single crystal X-ray diffraction. The single crystal X-ray analysis shows that the complex is a two-dimensional (2D) polymer and the dimensionality is further increased to 3D as a result of weak C-H???? and C-H??O interactions. |
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