Allylboration and cyclization of 3,4-dihydroisoquinoline derivatives. Synthesis of the benzopyrrocoline system |
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| Authors: | Yu. N. Bubnov A. Yu. Zykov A. V. Ignatenko A. G. Mikhailovsky Yu. V. Shklyaev V. S. Shklyaev |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp, 117913 Moscow, Russian;(2) Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, 13 ul. Lenina, 614600 Perm', Russian |
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| Abstract: | A novel approach to hexahydropyrrolo[2,1-alisoquinolines (hexahydrobe nzo[glpyrro-colines) based on the allylboration of 3,4-dihydroisoquinolines followed by closure of the pyrrolidine ring through the hydroboration — oxidation — intramolecularN-alkylation sequence was developed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 935–937, April, 1996. |
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| Keywords: | allylboration of azomethines 3,4-dihydroisoquinolines hydroboration hexahydropyrrolo[2,1-alisoquinolines |
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