| Synthesis and Crystal Structure of 1,4-Dimethyl-2,5-di{[2′-（3-pyridylmethylamino- formyl）phenoxyl]methyl}benzene Perchlorate |
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| 引用本文： | TANG Kuan-Zhen TANG Yu. Synthesis and Crystal Structure of 1,4-Dimethyl-2,5-di{[2′-（3-pyridylmethylamino- formyl）phenoxyl]methyl}benzene Perchlorate[J]. 结构化学, 2008, 27(4): 451-454 |
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| 作者姓名： | TANG Kuan-Zhen TANG Yu |
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| 作者单位： | TANG Kuan-Zhen（State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China） ;TANG Yu（State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China） ;LI Ya-Fei（State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China） ;LIU Wei-Sheng（State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China） ;TAN Min-Yu（State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China） ; |
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| 摘 要： | The title compound, 1,4-dimethyl-2,5-di { [2′-（3-pyridylmethylaminoformyl）phenoxyl]- methyl}benzene perchlorate （C36H36Cl2N4O12, Mr = 787.59）, has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal crystallizes in the orthorhombic system, space group Pbca with a = 14.366（4）, b = 15.159（4）, c = 16.443（5）A, V = 3580.9（17）/A3 Z = 4, De = 1.461 g/cm^3, /t = 0.253 mm^-1, F（000） = 1640, R = 0.0618 and wR = 0.1525 for 1615 observed reflections （I 〉 2σ（I））. In the structure of the title compound, a two-dimensional supramolecular layer is formed via intermolecular hydrogen bonding interactions.
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| 关 键 词： | 合成 晶体结构 1,4-二甲基 二吡啶甲基氨基甲酸 光谱分析 |
Synthesis and Crystal Structure of 1,4-Dimethyl-2,5-di {[2'-(3-pyridylmethylaminoformyl)phenoxyl]methyl}benzene Perchlorate |
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| TANG Kuan-Zhen,TANG Yu,LI Ya-Fei,LIU Wei-Sheng,TAN Min-Yu. Synthesis and Crystal Structure of 1,4-Dimethyl-2,5-di {[2'-(3-pyridylmethylaminoformyl)phenoxyl]methyl}benzene Perchlorate[J]. Chinese Journal of Structural Chemistry, 2008, 27(4): 451-454 |
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| Authors: | TANG Kuan-Zhen TANG Yu LI Ya-Fei LIU Wei-Sheng TAN Min-Yu |
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| Affiliation: | State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China |
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| Abstract: | The title compound, 1,4-dimethyl-2,5-di{[2'-(3-pyridylmethylaminoformyl)phenoxyl]-methyl}benzene perchlorate(C36H36Cl2N4O12, Mr = 787.59), has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal crystallizes in the orthorhombic system,space group Pbca with a = 14.366(4), b = 15.159(4), c = 16.443(5)(A), V = 3580.9(17)(A)3,Z = 4, Dc =1.461 g/cm3, μ = 0.253 mm-1, F(000) = 1640, R = 0.0618 and wR = 0.1525 for 1615 observed reflections (1＞2σ(I)). In the structure of the title compound, a two-dimensional supramolecular layer is formed via intermolecular hydrogen bonding interactions. |
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| Keywords: | 2 5-dimethyl-1 4-di{[2'-(3-pyridylmethylaminoformyl)phenoxyl]methyl}benzene synthesis spectral characterization crystal structure |
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