Reactions of α,β‐Enones with Diazo Compounds,Part 3 |
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Authors: | Olcay Ana Aye Daut
zdemir
zkan Sezer |
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Institution: | Olcay Anaç,Ayşe Daut Özdemir,Özkan Sezer |
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Abstract: | Carbonyl ylides arising from ethyl acetodiazoacetate/dimethyl diazomalonate and α,β‐enones with mainly s‐cis conformations underwent disrotatory cyclization to produce dihydrofuran derivatives. This process proved to be sensitive to steric effects. The corresponding ylides arising from rather s‐trans α,β‐enals yielded dioxole derivatives. The mechanisms of the reactions are discussed. |
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