The orientational ordering of benzyl alcohol in phospholipid bilayers |
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| Affiliation: | 1. Dept. of Earth and Planetary Sciences, Macquarie University, Sydney, Australia;2. Laboratoire de Géologie de Lyon, Ecole Normale Supérieure de Lyon, Université Claude Bernard Lyon 1, and CNRS, 69007 Lyon, France;1. Advanced Water Management Centre, the University of Queensland, St Lucia, QLD 4072, Australia;2. Département Génie Energétique et Environnement, INSA Lyon, 69621 Villeurbanne Cedex, France |
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| Abstract: | The α-methylene segment of benzyl alcohol has been deuterated at one site and the proton—deuterium dipole spin interaction measured for this compound dissolved in bilayers of dimyristoylphosphatidylcholine. These data, when combined with measured deuterium quadrupole interactions at other sites, allow for a more complete understanding of the orientational ordering and conformation of benzyl alcohol in the bilayers. Models for the rotary motion of the ring are discussed. |
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