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Critical behavior of dilute NaCl in H2O
Affiliation:1. U.S. Geological Survey, Earthquake Science Center, Seattle, WA, USA;2. Department of Geosciences, University of Arizona, Tucson, AZ, USA;3. U.S. Geological Survey, Geology Minerals Energy and Geophysics Science Center, Moffett Field, CA, USA
Abstract:The compositions of the saturated vapor and liquid phases are measured for the system NaCl-H2O at 380°C, which is close to the critical point of pure water. The shape of the phase equilibrium curve is classical, which confirms a conclusion reached earlier on the basis of less accurate data. This implies that the long-range forces introduced by the NaCl suppress the non-classical effects present in pure H2O. An empirical equation of a classical type fits these data.
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