Dichlorosilylene: rate constant for reaction with oxygen |
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| Affiliation: | 1. Department of Physics, St Francis Xavier University, Nova Scotia, Canada;2. Department of Physics, University of Toronto, Ontario, Canada |
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| Abstract: | Using the recently detected intense UV absorption spectrum of SiCl2(X̃1A1) the absolute rate constant has been measured for its reaction with oxygen. The value of the bimolecular rate constant, k(SiCl2 + O2), is equal to (3.4 ± 0.7) × 109 M−1 s−1 at 25° C. |
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