The concentration dependence of the phase of radical-pair mechanism chemically induced dynamic electron polarization (CIDEP) |
| |
| Affiliation: | 1. College of Civil Engineering, Tongji University, Shanghai, 200092, China;2. School of Environmental and Geographical Sciences, Shanghai Normal University, Shanghai, 200234, China;3. Department of Management and Economics, Tianjin University, Tianjin, 300072, China;4. College of Environmental Science and Engineering, Tongji University, Shanghai, 200092, China;5. State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai, 200092, China;6. Xinjiang Water Conservancy Science and Technology Extension Station, Urumqi, 830000, China;7. Department of Environmental Engineering, Faculty of Engineering and Green Technology, Universiti Tunku Abdul Rahman, 31900, Kampar, Perak, Malaysia |
| |
| Abstract: | In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here that the phase inversion is concentration dependent and that this removes the apparent inconsistencies. The results can be interpreted in two independent ways which at present cannot be distinguished. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
