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Multiphoton production and detection of N(2D)
Institution:1. Department of Chemical Physics, Fritz-Haber-Institute of the Max-Planck Society, Faradayweg 4-6, 14195 Berlin, Germany;2. Physik-Department E20, Technische Universität München, 85748 Garching, Germany
Abstract:N(2D) has been detected by resonance-enhanced multiphoton ionization (REMPI) at 269 nm in both the products of a microwave discharge in nitrogen (0.2–2%) in argon mixtures and as a result of two-photon dissociation of N2O. Further increase in the nitrogen fraction through the discharge decreased the N(2D) signal and finally replaced it with a series of molecular bands whose origin is thought to be electronically excited metastable states of N2.
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