Reactions of fluorine atoms with iodides studied by crossed beam laser-induced fluorescence |
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| Institution: | 1. School of Human Settlements and Civil Engineering, Xi’an Jiaotong University, 710049, China;2. Core Facilities and Experiment Center of Xi’an Jiaotong University, Xi’an Jiaotong University, 710049, China;1. Materials Science Centre, Indian Institute of Technology, Kharagpur, 721 302, India;2. School of Nano Science and Technology, Indian Institute of Technology, Kharagpur, 721 302, India;3. Department of Industrial and Manufacturing Systems Engineering, Kansas State University, Manhattan, KS, 66506, USA;4. Department of Electrical and Computer Engineering, Kansas State University, Manhattan, KS, 66506, USA |
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| Abstract: | The reactions of F atoms with C2H5I, C2F5I, and n-C3H5I were studied by the crossed beam laser-induced fluorescence techniques within the 570–620 nm wavelength region. The vibrational and rotational excitation spectra of the reaction product IF were measured. The relative vibrational population densities of v = 3,4, and 5 vibrational levels, and some of the relative detailed vibrational rate constants, the rotational temperatures, and the mean fractions of rotational energy in individual vibrational states of the reaction product IF were obtained. The reaction mechanism was discussed. |
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