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Transient esr observation of triplet-soliton pairs in a conjugated polymer single crystal
Affiliation:1. Département de Physique, Faculté des Sciences Exactes, Université Abderrahmane Mira, Bejaia 06000, Algeria;2. Laboratoire de Physique des Matériaux, Université Amar Telidji, BP 37G, Laghouat 03000, Algeria;3. Laboratoire de Recherche: Caractérisation et Valorisation des Ressources Naturelles, Université de Bordj Bou Arreridj, 34000, Algeria;4. Laboratory for Developing New Materials and their Characterization, University of Setif 1, Setif 19000, Algeria;5. Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia;1. International Laser Centre, Ilkovicova 3, 841 04 Bratislava, Slovakia;2. Institute of Electronics and Photonics, Slovak University of Technology, Ilkovicova 3, 812 19 Bratislava, Slovakia;3. Eberhard Karls Universität Tübingen, Institut für Physikalische und Theoretische Chemie, Auf der Morgenstelle 18, 72076 Tübingen, Germany;1. Department of Physics, Huazhong University of Science and Technology, Wuhan, PR China;2. Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan, PR China
Abstract:We have observed directly by pulsed ESR the formation and decay of a triplet state in a polydiacetylene single crystal after photoexcitation at 337 nm. The unusual spin polarization properties of the observed triplet suggest the formation of a tripletsoliton pair.
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