Magnetic circular dichroism measurements of the magnetisation properties of matrix-isolated species having spin angular momentum only |
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| Institution: | 1. Department of Chemistry, Drexel University, Philadelphia, PA 19104, USA;2. Department of Chemical and Biological Engineering, Drexel University, Philadelphia, PA 19104, USA;3. Centro de Ciências Naturais e Humanas, Universidade Federal do ABC, Santo André, SP 09210-580, Brazil |
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| Abstract: | Magnetic circular dichroism has been used for the first time to study the magnetisation properties of some matrix-isolated species. The samples chosen for measurement have one, three, five and six unpaired electrons in their ground electronic states and, nominally, no orbital angular momentum. The experimental results follow the theoretical predictions very closely, but the nature of the magnetisation function is such that it is not easy to distinguish between different combinations of g-value and total spin angular momentum. |
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