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Total synthesis of +-superstolide A |
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| Authors: | Tortosa Mariola Yakelis Neal A Roush William R |
| Institution: | Department of Chemistry, Scripps Florida, Jupiter, Florida 33458, USA. |
| Abstract: | A convergent and highly stereocontrolled synthesis of +-superstolide A (1) has been accomplished. Key steps of this synthesis include the intramolecular Suzuki reaction of 26 and the highly diastereoselective transannular Diels-Alder cyclization of macrocyclic octaene 3. |
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