Efficient synthesis of alpha-C-galactosyl ceramide immunostimulants: use of ethylene-promoted olefin cross-metathesis |
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| Authors: | Chen Guangwu Schmieg John Tsuji Moriya Franck Richard W |
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| Affiliation: | Department of Chemistry, Hunter College of CUNY, 695 Park Avenue, New York, New York 10021, USA. |
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| Abstract: | [reaction: see text] Olefin cross-metathesis has been used to prepare alpha-C-galactosylceramide derivatives. The metathesis process merged vinyl and propenyl glycosides with vinyl derivatives of phytosphingosine. The use of ethylene enhanced the yield of the methathesis step. |
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