Analytic equation of state for solids with multi-exponential potential based on analytic mean field potential approach and applied to the epsilon phase of solid oxygen |
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Authors: | Wang Li-Guo Sun Jiu-Xun and Yang Wei |
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Affiliation: | Department of Applied Physics, University of Electronic
Science and Technology, Chengdu 610054, China |
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Abstract: | The thermodynamic properties of the $\varepsilon $ phase of solid
oxygen are studied by using the analytic mean field approach (AMFP).
Analytic expressions for the Helmholtz free energy, internal energy
and equation of state of solid oxygen have been derived based on the
multi-exponential potential. The formulism for the case of
double-exponential (DE) model is applied to the $\varepsilon $ phase
of solid oxygen. Its four potential parameters are determined
through fitting the experimental compression data of the
$\varepsilon $ phase of solid oxygen. Numerical results of the
pressure dependence of the volume calculated by using the AMFP are
in good agreement with the original experimental data. This suggests
that the AMFP is a useful approach to study the thermodynamic
properties of the $\varepsilon $ phase of solid oxygen. Furthermore,
we predict the variation of the volume, lattice parameters and
intermolecular distances with pressure, and some thermodynamic
quantities versus volume, at several higher temperatures. |
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Keywords: | analytic equation of state analytic mean field approach solid oxygen $\varepsilon $ phase |
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