New approach to the synthesis of macrocyclic tetralactones via ring-closing metathesis using Grubbs' first-generation catalyst |
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| Authors: | Muthusamy Sengodagounder Gnanaprakasam Boopathy Suresh Eringathodi |
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| Institution: | School of Chemistry, Bharathidasan University, Tiruchirappalli, Tamilnadu 620 024, India. muthu@bdu.ac.in |
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| Abstract: | A facile and efficient route to synthesize macrocyclic tetralactones with different ring sizes having a wide variety of spacers is described. The application of ring-closing metathesis for the synthesis of macrocyclic tetralactones is demonstrated with many examples in excellent yield. The representative structure of macrocyclic tetralactones is characterized by X-ray crystallography. |
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