| 苯乙烯与N-取代马来酰亚胺的可逆加成-断裂链转移交替共聚合 |
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| 引用本文： | 方艳,曹赟,张爱萍,翟光群,孔立智,张东亮. 苯乙烯与N-取代马来酰亚胺的可逆加成-断裂链转移交替共聚合[J]. 高分子学报, 2010, 0(1): 51-58. DOI: 10.3724/SP.J.1105.2010.00051 |
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| 作者姓名： | 方艳 曹赟 张爱萍 翟光群 孔立智 张东亮 |
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| 作者单位： | 江苏工业学院材料科学与工程系,常州市高分子材料重点实验室,常州,213164 |
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| 基金项目： | 国家自然科学基金(基金号20674033);;江苏省自然科学基金(基金号BK2005404、BK2008142)资助项目 |
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| 摘 要： | 研究了二硫代苯甲酸酯存在下偶氮二异丁腈引发苯乙烯(St)、St与N-对羟基苯基马来酰亚胺(HPM)、St与N-对(2-氯/溴丙酰氧基)苯基马来酰亚胺(CPPM/BPPM)的可逆加成-断裂链转移(RAFT)均/共聚,聚合物的结构由紫外-可见光(UV-Vis)与凝胶渗透色谱(GPC)表征.结果表明,St的RAFT均聚以及St与N-取代马来酰亚胺的RAFT共聚均呈现活性聚合特征,分子量随着转化率上升而增加,且分子量分布较窄.对于St的RAFT均聚,由于双基终止,聚苯乙烯(PSt)链中"戴帽效率"随着转化率上升逐渐下降.对于St与N-取代马来酰亚胺的RAFT共聚合,电荷转移复合物的形成显著地提高了共聚反应速度,并促进交替结构的形成.随后进行了以P(St-alt-BPPM)引发St的原子转移自由基聚合以制备梳型PSt,结果表明在强极性溶剂中进行的聚合过程失去可控性,所得产物分子量极宽,而在本体聚合中所得聚合物分子量相对较窄,有一定的可控性.
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| 关 键 词： | 可逆加成-断裂链转移聚合 苯乙烯 N-取代马来酰亚胺 交替共聚物 原子转移自由基聚合 梳型高聚物 |
| 收稿时间： | 2009-01-04 |
RAFT ALTERNATING COPOLYMERIZATION OF STYRENE AND N-SUBSTITUTED MALEIMIDES |
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| FANG Yan,CAO Yun,ZHANG Aiping,ZHAI Guangqun,KONG Lizhi,ZHANG Dongliang. RAFT ALTERNATING COPOLYMERIZATION OF STYRENE AND N-SUBSTITUTED MALEIMIDES[J]. Acta Polymerica Sinica, 2010, 0(1): 51-58. DOI: 10.3724/SP.J.1105.2010.00051 |
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| Authors: | FANG Yan CAO Yun ZHANG Aiping ZHAI Guangqun KONG Lizhi ZHANG Dongliang |
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| Affiliation: | Key Laboratory of Polymeric Materials of Changzhou City;Department of Materials Science and Engineering;Jiangsu Polytechnic University;Changzhou 213164 |
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| Abstract: | The RAFT homopolymerization of St and copolymerization of St with N-substituted maleimides such as HPM,CPPM and BPPM,using AIBN as initiator,1-phenylethyl dithiobenzoate or cumyl dithiobenzoate as the chain transfer agent was investigated.The polymers were characterized by UV-Vis and GPC.The results suggested that both the homopolymerization and copolymerization exhibited a living behavior,and the molecular weight increased with the conversion and a narrow molecular weight distribution was achieved.For the ... |
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| Keywords: | RAFT Styrene N-Substituted Maleimide Alternating copolymer ATRP Comb-shaped polymer |
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