A novel glycosyl donor for chemo-enzymatic oligosaccharide synthesis: 4,6-dimethoxy-1,3,5-triazin-2-yl glycoside |
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Authors: | Tanaka Tomonari Noguchi Masato Kobayashi Atsushi Shoda Shin-Ichiro |
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Affiliation: | Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aoba, Sendai, 980-8579, Japan. |
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Abstract: | A novel activated glycosidic compound, 4,6-dimethoxy-1,3,5-triazin-2-yl beta-lactoside (DMT-beta-Lac), which can be prepared directly from lactose in water without using any protecting groups, was found to be an efficient glycosyl donor for enzymatic glycosylation catalyzed by an endo-1,4-beta-glucanase. |
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