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Synthesis and optical properties of conjugated dendrimers with unsymmetrical branching
Authors:Yongchun PanZhonghua Peng  Joseph S Melinger
Affiliation:a Department of Chemistry, University of Missouri—Kansas City, 5100 Rockhill Road, Kansas City, MO 64110, USA
b Naval Research Laboratory, Electronics Science and Technology Division, Code 6812, Washington, DC 20375, USA
Abstract:An improved synthetic approach to conjugated monodendrons with unsymmetrical branching structures is reported. Dendrimers containing two or three such conjugated monodendrons are synthesized and their optical properties are studied. Such dendrimers exhibit broad absorptions and very high fluorescence quantum yields, making them promising candidates for applications in molecular-based photonics.
Keywords:dendrimers   fluorescence   light-harvesting
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