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Synthesis and testing of new end-functionalized oligomers for molecular electronics |
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| Authors: | Austen K FlattShawn M Dirk Jay C HendersonDwanleen E Shen Jie SuMark A Reed James M Tour |
| Institution: | a Department of Chemistry and Center for Nanoscale Science and Technology, Rice University, 6100 Main Street, MS-222, Houston, TX 77005, USA b Departments of Electrical Engineering, Applied Physics, and Physics, Yale University, P.O. Box 208284, New Haven, CT 06520, USA |
| Abstract: | Several new classes of oligomers have been synthesized with functionalities designed to aid in the understanding of molecular device behavior, specifically when molecules are interfaced between proximal electronic probes. The compounds synthesized are series of azobenzenes, bipyridines and oligo(phenylene vinylene)s that bear acetyl-protected thiols for ultimate attachment to metallic surfaces. Some initial electrochemical and solid-state test results are also reported. |
| Keywords: | oligomers molecular electronics |
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