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A new ring-opening access to aeroplysinin-1, a secondary metabolite of Verongia aerophoba
Authors:Takahisa OgaminoShigeru Nishiyama
Affiliation:Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan
Abstract:An improved synthetic methodology of spiroisoxazolines by employing anodic oxidation of the corresponding phenol derivative has been established. An alternative efficient synthesis of aeroplysinin-1 1 has been achieved by employing the ring-opening reaction of spiroisoxazolines 10b, 10c as a key step.
Keywords:anodic oxidation   ring-opening reaction   aeroplysinin   Verongia aerophoba
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