Non-template synthesis of ‘N4’ di- and tetra-amide macrocylic ligands with variable ring sizes |
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Authors: | SJ Swamy B VeerapratapD Nagaraju K SureshP Someshwar |
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Institution: | Department of Chemistry, Kakatiya University, Vidyaranyapuri, Warangal 506 009, India |
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Abstract: | Nine new macrocyclic ligands containing two- or four-amide groups have been prepared by the cyclization reaction of three different diamines with acid chlorides (oxalyl dichloride or malonyl dichloride), diesters (diethyl oxalate or diethyl malonate) or 1,2-dichloroethane. The macrocycles prepared are four tetraaza-14-crown-4, four tetraaza-15-crown-4 and one tetraaza-16-crown-4. All the macrocyclic ligands were characterized by elemental analysis and, IR, UV, NMR and mass spectral investigations. |
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Keywords: | macrocyclic ligands tetraaza macrocycles amide ligands non-template synthesis |
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