Synthesis of sugar-based ethenyl ethers through a vinyl bis-sulfone methodology |
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| Authors: | Florence Ché ryMatthieu Desroses,Arnaud Tatibouë tOttorino De Lucchi,Patrick Rollin |
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| Affiliation: | a Institut de Chimie Organique et Analytique, UMR CNRS 6005, Université d'Orléans, B.P. 6759, F-45067 Orléans, France
b Dipartimento di Chimica, Universita Ca'Foscari di Venezia, Dorsoduro 2137, I-30123 Venezia, Italy |
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| Abstract: | The recently devised route to ethenyl ethers—i.e. 1,2-bis(phenylsulfonyl)ethylene (BPSE)-mediated conversion of alcohols into β-alkoxyvinyl sulfones followed by reductive desulfonylation—has been applied in the carbohydrate field to the synthesis of a number of vinyl-functionalised monosaccharides, a number of which had not been prepared via alternative routes. |
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| Keywords: | carbohydrates alkoxyvinylsulfones ethenyl ethers desulfonylation |
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