|
|||||
|
|
Unexpected reactivity of oxygenated 2-acyl-1,3-dithianes with electrophiles |
|
| Authors: | Michael SmietanaAlain Valleix Charles Mioskowski |
| Affiliation: | a Laboratoire de Synthèse Bio-organique, CNRS and Université Louis Pasteur, Faculté de Pharmacie, 74 Route du Rhin, 67401 Illkirch, France b CEA/Saclay, Service des Molécules Marquées, Bat. 547, Département de Biologie Cellulaire et Moléculaire, 91141 Gif/Yvette cedex, France |
| Abstract: | Lithium enolates of oxygenated acyl-dithiane undergo unexpected regiospecific reactions with electrophiles. Reaction of aldehydes with oxygenated acyl-dithiane leads to the formation of the corresponding monosubstituted β-hydroxy-acyl-dithiane. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |