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New odorless method for the Corey-Kim and Swern oxidations utilizing dodecyl methyl sulfide (Dod-S-Me) |
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| Authors: | Shin-ichi OhsugiKiyoharu Nishide Keiji OonoKazunori Okuyama Masato FudesakaSumiaki Kodama Manabu Node |
| Affiliation: | a Kyoto Pharmaceutical University, Misasagi, Yamashina, Kyoto 607-8414, Japan b Wako Pure Chemical Industries, Ltd, 1633 Matoba, Kawagoe, Saitama 350-1101, Japan |
| Abstract: | Development of the odorless dodecyl methyl sulfide (Dod-S-Me, 1) as an alternative for dimethyl sulfide (DMS) and new odorless methods for the Corey-Kim and Swern oxidations are described. These reactions have been developed with a view toward green chemistry, utilizing Dod-S-Me (1) and common solvents instead of dichloromethane. |
| Keywords: | odorless Corey-Kim oxidation dodecyl methyl sulfide odorless Swern oxidation dodecyl methyl sulfoxide |
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