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Artificial model for cystathionine β-synthase: construction of a catalytic cycle with a pyridoxal model compound having an ionophore function |
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| Authors: | Kazuyuki MiyashitaHidenobu Murafuji Hiroshi IwakiEito Yoshioka Takeshi Imanishi |
| Affiliation: | Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan |
| Abstract: | Catalytic transformation of serine-O-carbonate to S-aryl cysteine derivatives was successfully achieved in the presence of Li+ by the use of a pyridoxal model compound having an ionophore function, which is the first example mimicking cystathionine β-synthase, artificially. |
| Keywords: | amino acids and derivatives coenzymes pyridines substitution |
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