Synthesis of a new class of electron rich chiral cyclophanes with large cavities |
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| Authors: | Perumal Rajakumar |
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| Institution: | Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai-600 025, India |
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| Abstract: | BINOL based electron rich chiral cyclophanes possessing large cavities have been synthesized starting from m-terphenyl dibromide and methyl m-/p-cinnamate. The presence of double bonds in the chiral cyclophanes makes them electron rich as revealed by C-T complexation studies of such cyclophanes donors with guests like TCNE, TCNQ and DDQ. |
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| Keywords: | chiral cyclophanes electron rich large cavities |
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