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Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions
Authors:Abirami Srikanth  Gopalpur NagendrappaSrinivasan Chandrasekaran
Affiliation:a Department of Organic Chemistry, Indian Institute of Science, C. V. Raman Avenue, Bangalore 560012, India
b Department of Chemistry, Bangalore University, Central College campus, Bangalore 560001, India
Abstract:A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of -SiMe3 group on the rate of epoxidation process.
Keywords:epoxidation   ruthenium   vinylsilanes   molecular oxygen
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