Highly efficient syntheses of 3-aryl-2-cycloalken-1-ones and an evaluation of their liquid crystalline properties |
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| Authors: | C.M MarsonR Brettle D.A Dunmur |
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| Affiliation: | Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK |
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| Abstract: | Cycloalkenones are shown to be mesogens and can be synthesised in near quantitative yields by a convergent palladium(0)-catalysed cross-coupling strategy; a 2-methyl group induces a change of phase from smectic to nematic. |
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| Keywords: | palladium(0) arylboronic acids cycloalkenone |
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