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Cationic rhodium(I) and iridium(I,III) complexes of cinnamonitrile and their catalytic activities |
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| Authors: | Kyung Joon Yang In Bum Kim Chong Shik Chin |
| Affiliation: | (1) Department of Chemistry, Sogang University, CPO Box 1142, 121 Seoul, Korea |
| Abstract: | Summary Reactions of cinnamonitrile (trans-PhCH=CHCN) with [M(ClO4)(CO)(PPh3)2] (M=Rh or Ir) produce hydrogenation oftrans-PhCH=CHCN to PhCH2CH2CN at 100°C under 3 atm of hydrogen. |
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