| 高分子钼铁硫原子簇催化剂的合成反应及其结构表征 |
| |
| 引用本文： | 孙春亭,黄启军,牛淑云,李淑芹.高分子钼铁硫原子簇催化剂的合成反应及其结构表征[J].高分子学报,1982,0(4):248-252. |
| |
| 作者姓名： | 孙春亭 黄启军 牛淑云 李淑芹 |
| |
| 作者单位： | 吉林大学化学系
(孙春亭，黄启军，牛淑云)，吉林大学化学系(李淑芹) |
| |
| 摘 要： | 以乙烯基吡啶的共聚物为高分子载体,用固相合成的方法,通过多步反应合成了一个高分子钼铁硫原子簇催化剂。用紫外可见光谱和红外光谱分析研究了该催化剂的结构,并说明它具有原子簇结构。本催化剂在KBH_4还原剂存在下,对乙炔加氢反应具有催化活性,可以循环使用。
|
| 收稿时间： | 1981-05-29 |
THE SYNTHESIS AND CHARACTERIZATION OF A VINYLPYRIDINE-COPOLYMER COORDINATED CLUSTER CATALYST OF MOLYBDENUM-IRON-SULFUR |
| |
| Sun Chun-ting,Huang Qi-jun,Niu Shu-yun,Li Shu-qin.THE SYNTHESIS AND CHARACTERIZATION OF A VINYLPYRIDINE-COPOLYMER COORDINATED CLUSTER CATALYST OF MOLYBDENUM-IRON-SULFUR[J].Acta Polymerica Sinica,1982,0(4):248-252. |
| |
| Authors: | Sun Chun-ting Huang Qi-jun Niu Shu-yun Li Shu-qin |
| |
| Institution: | Department of Chemistry; Jilin University |
| |
| Abstract: | A new vinylpyridine-copolymer coordinated cluster catalyst of molybdenum-iron-sulfur has been prepared by means of solid state synthesis through multistep reaction. The structure of this catalyst has been identified as cluster structure by UV-visible and infrared spectra. The polymeric catalyst has catalystic reactivity for acetylene hydrogenation, and can be used repeatedly. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
|
