Urotropin synthesis of 3,5-di-tert-butylsalicylic acid derivatives |
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| Authors: | V. B. Vol’eva I. S. Belostotskaya N. L. Komissarova L. N. Kurkovskaya A. P. Pleshakova T. I. Prokofeva |
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| Affiliation: | (1) Emmanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia;(2) Nesmeyanov Institute of Organoelemental Compounds, Moscow, Russia |
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| Abstract: | The stability of 3,5-di-tert-butylsalicylic aldehyde against oxidation is due to autoinhibiting of the chain process. However its oxidation into 3,5-di-tert-butylsalicylic acid was performed at the use of acetyl protection of the hydroxy group. In reaction of 6-bromo-2,4-di-tert-butylphenol with urotropin the formation was discovered of 3,5-di-tert-butylsalicylic acid, its nitrile and amide. |
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