Regioselective directed ortho metalation of 3H-naphto[2,1-b]pyrans. Synthesis of methylteretifolione B |
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| Affiliation: | 1. State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming, 650201, People''s Republic of China;2. University of Chinese Academy of Sciences, Beijing, 100049, People''s Republic of China;3. Yunnan Key Laboratory of Natural Medicinal Chemistry, Kunming, 650201, People''s Republic of China;1. Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Mlynská dolina, Ilkovičova 6, 842 15 Bratislava, Slovak Republic;2. Institute of Electronics and Photonics, Slovak University of Technology, Ilkovičova 3, 812 19 Bratislava, Slovak Republic;3. Institute of Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Mlynská dolina, Ilkovičova 6, 842 15 Bratislava, Slovak Republic;4. Institute of Physics, Slovak Academy of Sciences, Dúbravská cesta 9, 845 11 Bratislava, Slovak Republic;5. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, Slovak Republic;6. Institute of Nuclear and Physical Engineering, Slovak University of Technology, Ilkovičova 3, 812 19 Bratislava, Slovak Republic;1. Laboratory of Organic Synthesis, Department of Chemistry, Govt. Degree College for Women Baramulla, Jammu & Kashmir 193101, India;2. Department of Biochemistry, University of Kashmir, Srinagar, Jammu & Kashmir 190006, India;3. Department of Chemistry, Faculty of Science, SHUATS Allahabad, Uttar Pradesh 211007, India;4. Academy of Scientific and Innovative Research (AcSIR), New Delhi 110012, India;5. Department of Biochemistry, Faculty of Medicine, Jawaharlal Nehru Medical College, Aligarh Muslim University, UP 190006, India |
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| Abstract: | The regiospecific lithiation of the 3H-naphtho[2,1-b]pyran system 1 b andits utility as a metalted tertifolione B equivalent 3 is described. |
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