Spectroscopic properties of the vanadium(III) tris(metaphosphate), V(PO3)3 |
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| Affiliation: | 1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain;1. GE Global Research, One Research Circle, Niskayuna, NY 12309, United States;2. University at Albany-SUNY, Department of Chemistry, 1400 Washington Avenue, Albany, NY 12222, United States |
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| Abstract: | A vanadium(III) tris(metaphosphate) compound has been synthesized and characterized. The compound crystallises in the monoclinic space group Ic with lattice parameters a= 10.615(2), b= 19.095(4), c= 9.432(1) Å, β= 97.94(1) °. IR and UV-V studies confirm a chain structure for this compound. The ESR powder spectrum shows a weak signal belonging to the V3+ ions. The D parameter value has been estimated between 2 and 8 cm−1. |
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