One-dimensional indium sulfides with transition metal complexes of polyamines |
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Authors: | Zhou Jian Bian Guo-Qing Zhang Yong Zhu Qin-Yu Li Chun-Yin Dai Jie |
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Affiliation: | Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou, PR China. |
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Abstract: | Three new indium sulfides, [Ni(dien)2]0.5[InS2] (dien = diethylenetriamine) (1), [Ni(dap)3]0.5[InS2] (dap = 1,2-diaminopropane) (2), and [Ni(tepa)]2[In4S7(SH)2].H2O (tepa = tetraethylenepentamine) (3), have been prepared under solvothermal conditions and characterized by single-crystal X-ray diffraction. Compounds 1 and 2 consist of discrete 1-D {[InS2]-} infinity chains with complex cations as charge-compensating ions, while compound 3 consists of a novel 1-D anionic chain constructed from arachno-shaped In4S11 clusters. The sulfide chain of 3 coordinates into the complex cations via the nonterminal S atoms of the polymeric anion, forming a covalently linked organic-inorganic hybrid compound. |
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