| 替代微分形式的雅可比热力学变换式(英文) |
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| 引用本文： | 邝钜炽,张军.替代微分形式的雅可比热力学变换式(英文)[J].华南理工大学学报(自然科学版),2001(3). |
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| 作者姓名： | 邝钜炽 张军 |
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| 作者单位： | 佛山科学技术学院化学系!广东佛山528000(邝钜炽)，佛山石湾东建陶瓷厂!广东佛山528000(张军) |
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| 摘 要： | 结合雅可比行列式和热力学变量的特性 ,率先导出了三个极为重要的雅可比热力学变换式 ,除 (12 )式外 ,其余尚未见报道 .雅可比热力学变换的重要意义不仅体现在它为我们提供了一种证明难题的便利工具 ,而且还体现在其揭示了热力学变量间的内在联系 ,或预告某热力学量随其它热力学量变化的情况 ,显然此用微分法往往难以实现
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| 关 键 词： | 雅可比表达式(雅可比行列式) 微分法 麦克斯韦关系式 热力学 |
Jacobian's Thermodynamic Transforms Replacing Differentiation |
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| Kuang Ju_chi,Zhang Jun.Jacobian's Thermodynamic Transforms Replacing Differentiation[J].Journal of South China University of Technology(Natural Science Edition),2001(3). |
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| Authors: | Kuang Ju_chi Zhang Jun |
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| Institution: | Kuang Ju_chi 1 Zhang Jun 2 |
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| Abstract: | The noteworthy work in this article consists in combining characters of thermodynamic variables with Jacobian determinants to develop the three significant J transforms of thermodynamics,which seem not to have been reported except Eq.(12) until now.The significance of them is not only to offer us a new convenient tool for proofing puzzle but also to reveal the inner interrelations of thermodynamic variables,or to foretell the rules of variation of any thermodynamic variable following others.By all appearances,this can hardly be done by way of differentiation. |
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| Keywords: | J (Jacobian) differentiation Maxwell Relations thermodynamic |
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